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焦炉烟气钢渣湿法联合脱硫脱硝试验研究(4)

来源:湿法冶金 【在线投稿】 栏目:期刊导读 时间:2021-01-18
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摘要:2)浆液浓度升高会增大体系pH值,促进NO脱除;烟气流量增加,即停留时间降低会减少气液接触时间,导致脱硫脱硝效率降低,因此在考虑处理成本的同时应

2)浆液浓度升高会增大体系pH值,促进NO脱除;烟气流量增加,即停留时间降低会减少气液接触时间,导致脱硫脱硝效率降低,因此在考虑处理成本的同时应增加停留时间。

3)实验室最优反应条件下(温度30 ℃,浆液浓度8%,烟气流量400 mL/min),脱硝率为50.7%,脱硫率高于95%。

4)NOx的脱除主要是钢渣浆液吸收了NO与O2反应生成的NO2,以及NO2与NO结合的N2O3。通过气相预氧化将部分NO氧化为NO2,然后NO2以及剩余的NO和NO2结合的N2O3可被钢渣浆液快速高效的吸收。

5)现有钢渣脱硫脱硝技术的脱硝效率偏低,通过强化脱硝手段,可实现NOx排放达标甚至超低排放标准,有利于钢渣湿法联合脱硫脱硝的工程化应用。

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